4족과 13족 금속 화합물을 위한 다기능성 Dicarbollide Ligand계의 합성
- Issued Date
- 2009
- Abstract
- A series of group 4 metal complexes with p,s-type bonding interaction of the formula [{R(h5-C2B9H9)(CH2)(h1-NMe2)}M(NMe2)2] (R = CH2NMe2, M = Ti 7, Zr 8; R = PPh2, M = Ti 9, Zr 10), was produced by the reaction of group 4 metal amides (M(NMe2)4; M = Ti, Zr) with the multi-functionalized dicarbollyl ligands, nido-7,8-C2B9H10-7,8-[(m-H)NMe2(CH2)]2 (3) and nido-7,8-C2B9H10-[(m-H)PPh2NMe2CH2] (6), respectively.
- Alternative Title
- Multi-Functionalized dicarbollide Ligand Systems for Group 4 and 13 Metal complexes
- Alternative Author(s)
- Kim, Ha-Yeon
- Affiliation
- 조선대학교
- Department
- 일반대학원 화학과
- Advisor
- 이종대
- Awarded Date
- 2010-02
- Table Of Contents
- Contents
1.Abstract (영문)
2.Abstract (국문)
3.Introduction
4.Results and Discussion
5.Experimental Section
5.1. General Procedure
5.2. Preparation of [closo-1,2-(CH2NMe2)2-1,2-C2B10H10] 2
5.3. Preparation of [nido-7,8-(NMe2CH2)2-7,8-C2B9H10]3
5.4. Preparation of [closo-1-PPh2-2-CH2NMe2-1,2-C2B10H10]5
5.5. Preparation of [nido-7-PPh2-8-CH2NMe2-7,8-C2B9H10]6
5.6. Preparation of [h5:h1-(NMe2CH2C2B9H9CH2NMe2)]Ti(NMe2)2 7
5.7. Synthesis of 8
5.8. Synthesis of 9
5.9. Synthesis of 10
5.10. Preparation of [(h1-NMe2CH2C2B9H10)CH2(h1-NMe2)]AlMe2 11
5.11. Synthesis of 12
5.12. Synthesis of 13
5.13. Synthesis of 14
5.14. Crystal Structure Determination
6.References
7.Table 1. Comparison of the NMR Spectroscopic Data for Compounds 3, 6, and 7−14
8.Figures
9.X-ray Data
10.저작물 이용 허락서
11.감사의 글
- Degree
- Master
- Publisher
- 조선대학교
- Citation
- 김하연. (2009). 4족과 13족 금속 화합물을 위한 다기능성 Dicarbollide Ligand계의 합성.
- Type
- Dissertation
- URI
- https://oak.chosun.ac.kr/handle/2020.oak/8366
http://chosun.dcollection.net/common/orgView/200000239134
- Appears in Collections:
- General Graduate School > 3. Theses(Master)
- Files in This Item:
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