Synthesis of Allyl Functionalized Silacrown Ethers and Their Application - A Review

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Md Hasanul Haque Honglae Sohn
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Silacrown Ethers Ion-selective electrodes Dendrimers Ionophore
A study is reported about the synthesis processes of various silacrown ether by the reaction of alkoxysilanes with polyethylene glycols (PEG) through transesterification. Crown ether-functionalized carbosilane dendrimers and hybrid crown ethers are also discussed. We will also address the solubility enhancement, phase-transfer catalysis of different silacrown as well as their application as Ion-selective electrodes (ISEs) and as active phase of PVC electrodes for the development of potentiometric sensors for detection of alkali-Ions.
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