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Reactions of 1,1-Dichloro-2,3,4,5-Tetraphenyl-1-Silacyclopentadiene with Magnesium and Lithium

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Author(s)
Jang-Hwan Hong
Issued Date
2019
Keyword
Metalloles Silole Silolylene Magnesium α-Elimination
Abstract
The reaction of 1,1-dichloro-2,3,4,5-tetraphenyl-1-silacyclopentadiene (1) with magnesium-amalgam in THF gave octaphenyl-1,1′-spirobisilole (2), so it was suggested that octaphenyl-1,1′-spirobisilole (2) was produced via the corresponding silolylene species
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