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염화칼슘 수용액에서 철강의 부식에 미치는 부식억제제(아질산나트륨, 헥사메탄인산염, 트리에탄올아민, 설탕, 요소)의 영향

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Author(s)
박태준
Issued Date
2018
Abstract
Abstract

Effects of inhibitors (sodium nitrite, sodium hexametaphosphate, triethanolamine, sugar, and urea) on the corrosion of steel in a calcium chloride solution

Tae Jun Park
Advisor: Prof. HeeJin Jang, Ph. D.
Dept. of Advanced Materials Engineering
Graduate School of Chosun University



Various kinds of corrosion inhibitors are added to deicing salt in order to reduce its corrosivity and we need to optimize the concentration of each additive to reach the low corrosivity and high deicing ability simultaneously. RSM (Response Surface Methodology), a type of DOE (Design of Experiment technique), was applied to examine the effects of each additive and find the optimum composition of the deicing agent. NaNO2, (NaPO3)6, TEA(Triethylamine), sugar, and urea were used asadditives in this study. CaCl2-based test solutions with these additives of different concentrations were designed by RSM. The corrosionrate of steels heet was e valuated in the test solutions by electrochemical potentiodynamic polarization tests. A statistical model was obtained for the corrosionrate, suggesting the main effect of each additive and interactions between additives quantitatively
Alternative Title
Effects of inhibitors (sodium nitrite, sodium hexametaphosphate, triethanolamine, sugar, and urea) on the corrosion of steel in a calcium chloride solution
Alternative Author(s)
tae jun park
Department
일반대학원 첨단소재공학과
Advisor
장희진
Awarded Date
2018-08
Table Of Contents
목 차

LIST OF TABLES ⅳ
LIST OF FIGURES ⅴ
ABSTRACT ⅸ

제 1 장 서 론 1
제 2 장 이론적 배경 3
제 1 절 제설제 3
1. 제설제의 사용 목적과 기능 3
2. 제설제의 종류 및 특성 4

제 2 절 부식억제제 6
1. 부식억제제의 작용원리 6
2. 부식억제제의 종류 9

제 3 절 구조용 콘크리트 부식 12
1. 부식 12
2. 부식의 원인 및 종류 13
3. 철의 부식 16
4. 부동태 18
5. 콘크리트 부식의 메커니즘 22

제 4 절 반응표면 분석법 25
1. 실험계획법 25
2. 회귀 분석 29
2. 분산 분석 32

제 3 장 실험방법 34
제 1 절 전기화학 분석 34
제 2 절 반응표면분석법 36

제 4 장 결과 및 고찰 39
제 1 절 결과 39
1. 전기화학 분석 39
2. 반응표면분석법 44

제 2 절 고찰 51
1. 부식억제제의 주효과와 상호효과 51
2. 최적의 조성 56

제 5 장 결 론 59
참 고 문 헌 60
Degree
Master
Publisher
조선대학교 대학원
Citation
박태준. (2018). 염화칼슘 수용액에서 철강의 부식에 미치는 부식억제제(아질산나트륨, 헥사메탄인산염, 트리에탄올아민, 설탕, 요소)의 영향.
Type
Dissertation
URI
https://oak.chosun.ac.kr/handle/2020.oak/13655
http://chosun.dcollection.net/common/orgView/200000266960
Appears in Collections:
General Graduate School > 3. Theses(Master)
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