DBR 다공성 실리콘을 이용한 나프타 센서 개발과 Silole과 실리콘 양자점 사이의 형광 공명에 대한 연구
- Issued Date
- 2015
- Abstract
- Chapter 2. Silicon Quantum Dots (SiQDs) derivatized with organic fluorophore such as siloles were successfully synthesized from the reaction of ammonium chloride, magnesium silicide, and 1-chloro-1-methyl-2,3,4,5-tetraphenyl-silole in DMF. Optical characterizations of SiQDs were achieved by using ultraviolet-visible (UV-Vis) and photoluminescence (PL) spectroscopy. Silole-derivatized SiQDs were characterized by nuclear magnetic resonance (NMR). SiQDs synthesized without silole were emitted the light at 460 nm with an excitation wavelength of 400 nm. The emission wavelength of 1-chloro-1-methyl-2,3,4,5-tetraphenyl-silole is 500 nm with an excitation wavelength of 360 nm. After the synthesis of Si QD/silole nanoparticles, Si QD/silole nanoparticles were subjected to measure the PL. Detailed information about the photoluminescence will be discussed.
- Alternative Title
- Development of Naphtha Sensor Based on DBR Porous Silicon and Fluorescence Resonance Study between Silole and Silicon Quantum Dots
- Alternative Author(s)
- Kim Kang Bin
- Affiliation
- 조선대학교 화학과
- Department
- 일반대학원 화학과
- Advisor
- 손홍래
- Table Of Contents
- TABLE OF CONTENTS
TABLE OF CONTENTS ⅰ
LIST OF SYMBOLS AND ABBREVIATIONS ⅳ
LIST OF TABLES ⅴ
LIST OF SCHEMES ⅵ
LIST OF FIGURES ⅶ
ABSTRACT ⅷ
Development of Naphtha Sensor Based on DBR Porous Silicon and Fluorescence Resonance Study between Silole and Silicon Quantum Dots
Chapter One. Development of Naphtha Sensor Based on DBR Porous Silicon
1.Introduction 2
2.Experimental Section 4
2.1.Materials & Instrument 4
2.1.1.Materials 4
2.1.2.Instrument 4
2.2.Experiments 5
2.2.1.Preparation of DBR porous silicon sample 5
2.2.2.Bench setup and detection of naphtha by vapor pressure under white light 6
2.2.3.Wavelength shifts of DBR porous silicon for naphtha vapor 7
2.2.4.Reproducibility as sensor under laser 7
3.Results and Discussion 8
3.1.Result of DBR porous silicon fabrication 8
3.1.1.Measurement of reflectivity spectra 8
3.1.2.Measurement of SEM image 8
3.2.Detection of naphtha vapor 9
3.2.1.Detection of naphtha by vapor pressure 9
3.2.2.Relationship between vapor pressure and wavelength shift 10
3.3.Reproducibility as sensor 11
3.3.1.Reproducibility as sensor under Laser 11
4.Conclusion 12
5.References 13
Chapter Two. Fluorescence Resonance Study between Silole and Silicon Quantum Dots
1.Introduction 16
2.Experimental 17
2.1.Generals 17
2.2.Synthesis of silole compounds 17
2.2.1.Synthesis of 1-chloro-1-methyl-2,3,4,5-tetraphenyl-silole 17
2.2.2.Synthesis of 1-hyroxy-1-methyl-2,3,4,5-tetraphenyl-silole 18
2.2.3Synthesis of 1-methyl-1-(1-methyl-2,3,4,5-tetraphenyl-silol-1-yl)oxy-2,3,4,5-tetraphenyl-silole 18
2.3.Synthesis of silicon quantum dots 19
2.3.1.Synthesis of silicon quantum dots (solvent DMF) 19
2.3.2.One-Pot synthesis of silicon quantum dots / silole 19
3.Results and Discussion 21
3.1.Preparation of silole compound 21
3.1.1.Synthesis of 1-chloro-1-methyl-2,3,4,5-tetraphenyl-silole 21
3.1.2Synthesis of 1-hyroxy-1-methyl-2,3,4,5-tetraphenyl-silole 22
3.1.3Synthesis of 1-methyl-1-(1-methyl-2,3,4,5-tetraphenyl-silol-1-yl)oxy-2,3,4,5-tetraphenyl-silole 23
3.2.PL spectrum data 24
3.2.1.Silicon quantum dots PL data 24
3.2.2.Silole PL data 25
4.Conclusion 26
5.References 27
6.Appendix 28
- Degree
- Master
- Publisher
- 조선대학교
- Citation
- 김강빈. (2015). DBR 다공성 실리콘을 이용한 나프타 센서 개발과 Silole과 실리콘 양자점 사이의 형광 공명에 대한 연구.
- Type
- Dissertation
- URI
- https://oak.chosun.ac.kr/handle/2020.oak/12377
http://chosun.dcollection.net/common/orgView/200000264556
- Appears in Collections:
- General Graduate School > 3. Theses(Master)
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DBR 다공성 실리콘을 이용한 나프타 센서 개발과 Silole과 실리콘 양자점 사이의 형광 공명에 대한 연구.pdf
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