박막태양전지 광흡수층 제조를 위한 비정질 CuSe2 박막 특성

Abstract

Laser-induced doping of amorphous copper diselenide (α-CuSe2) thin film with gallium (Ga) and indium (In) was performed to control/improve their electrical and optical properties. The CuSe2 thin films sputtering-deposited using a CuSe2 alloy target were amorphous and remained amorphous after doping with Ga/In. Doping of group-III-elements enhanced the absorption ability of the α-CuSe2 thin films in the near-infrared spectral regions (800 - 1500 nm). The insufficient laser-irradiation time to Ga attributed the non-uniform distribution of Ga content around the surface of the α-CuSe2 thin films, which prevented the incident light from transiting through the thin film, particularly in the visible spectral region (400-800 nm). Consequently, the absorption coefficient increased with the non-uniformly distributed specimen in the visible and near-infrared spectral regions, which improved the mean absorbance of the α-CuSe2 thin films from 1.03 to 1.66 by decreasing the optical band gap energy from 2.50 to 2.10 eV in the same spectral region. The resistivity, carrier concentration and carrier mobility of the α-CuSe2 thin films were in 3.76×10-4 - 3.83×10-3Ω-cm, 1.41×1020 - 2.00×1021 cm-3 and 9.9 - 19.4 cm2/Vs, respectively, regardless of doping, making these films suitable as a wide spectral range absorber layer in photovoltaic applications.